image: Inspired by the warming Earth’s greenhouse effect, we design a catalyst architecture that enables waves selectively to pass through. This greenhouse mimic is composed of a carbonized MOF core with a mesoporous silica sheath. When bathed in sunlight, the black core generates heat, which is trapped therein by the infrared shielding effects of the mesopores, thus boosting the recycling efficiency of waste plastics. view more
Credit: Chinese Journal of Catalysis
Photothermal catalysis, fueled by clean solar energy, offers an efficient solution for converting waste plastic into valuable chemicals. This catalytic process harnesses the power of solar energy and converts it into chemical energy. However, the development of photothermal catalysts that exhibit high conversion efficiency and catalytic activity poses significant challenges.
A recent breakthrough comes from a research team led by Prof. Jinxing Chen from Soochow University, China. They have successfully developed an integrated photothermal catalyst comprising c-ZIF-8 coated with a SiO2 layer. This innovative approach focuses on enhancing catalytic activity by minimizing thermal radiation loss and maximizing the localized heating effect of the catalyst. The results were published in Chinese Journal of Catalysis (https://doi.org/10.1016/S1872-2067(23)64435-3).
This study introduces a novel catalyst design approach that involves the synthesis of ZIF-8 nanoparticles using a template method. To create an integrated photothermal catalyst (c-ZIF-8@SiO2), a layer of SiO2 is coated onto the surface of ZIF-8, followed by a high-temperature carbonization treatment. The internal carbon material within the catalyst absorbs solar energy and generates heat, while the outer SiO2 layer selectively allows penetration of solar light, which is then absorbed by the carbon core. This design effectively reduces thermal radiation loss from the internal carbon core and enhances the local thermal effect during the photothermal catalysis process. Furthermore, the SiO2 shell provides a protective effect, resulting in the catalyst's high stability. Overall, this catalyst design strategy offers a universal method for enhancing the local thermal effect in photothermal catalysis and holds potential applications in the development of efficient photothermal catalytic systems.
By irradiating sunlight, the c-ZIF-8@25SiO2 catalyst can efficiently upcycle PET into valuable monomers. The PET glycolysis experiment under outdoor sunlight and the selective recovery of PET from mixed plastics further demonstrate the promising applications in photothermal catalytic PET glycolysis. Photothermal catalysis not only contributes to energy conservation and emission reduction, promoting green and sustainable development but also provides new ideas and methods for efficient chemical recycling of plastics.
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About the Journal
Chinese Journal of Catalysis is co-sponsored by Dalian Institute of Chemical Physics, Chinese Academy of Sciences and Chinese Chemical Society, and it is currently published by Elsevier group. This monthly journal publishes in English timely contributions of original and rigorously reviewed manuscripts covering all areas of catalysis. The journal publishes Reviews, Accounts, Communications, Articles, Highlights, Perspectives, and Viewpoints of highly scientific values that help understanding and defining of new concepts in both fundamental issues and practical applications of catalysis. Chinese Journal of Catalysis ranks at the top one journal in Applied Chemistry with a current SCI impact factor of 16.5. The Editors-in-Chief are Profs. Can Li and Tao Zhang.
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Journal
Chinese Journal of Catalysis